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Binuclear complexes containing barbituric derivatives as ligands-precursors for supramolecular structures. I. Synthesis and spectral properties of N,N’-bis-(5,5’-diethyl-barbituryl-1-methyl)-piperazine (VEP) and its copper(II) complex [articol]

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dc.contributor.author Bucovicean, Carmen Maria
dc.contributor.author Tudose, Ramona
dc.contributor.author Costișor, Otilia
dc.date.accessioned 2020-04-03T10:12:02Z
dc.date.accessioned 2021-03-01T08:54:00Z
dc.date.available 2020-04-03T10:12:02Z
dc.date.available 2021-03-01T08:54:00Z
dc.date.issued 2005
dc.identifier.citation Bucovicean, Carmen Maria. Binuclear complexes containing barbituric derivatives as ligands-precursors for supramolecular structures. I. Synthesis and spectral properties of N,N’-bis-(5,5’-diethyl-barbituryl-1-methyl)-piperazine (VEP) and its copper(II) complex. Timişoara: Editura Politehnica, 2005 en_US
dc.identifier.uri http://primo.upt.ro:1701/primo-explore/fulldisplay?docid=40TUT000136572&context=L&vid=40TUT_V1&lang=ro_RO&search_scope=40TUT&adaptor=Local%20Search%20Engine&tab=default_tab&query=any,contains,Binuclear%20complexes%20containing%20barbituric%20derivatives%20as%20ligands-precursors%20for%20supramolecular%20structures.%20I.%20Synthesis%20and%20spectral%20properties%20of%20N,N%E2%80%99-bis-(5,5%E2%80%99-diethyl-barbituryl-1-methyl)-piperazine%20(VEP)%20and%20its%20copper(II)%20complex%20%5B&sortby=rank&offset=0 Link Primo
dc.description.abstract The new Mannich base VEP (N,N’-bis-(5,5’-diethyl-barbituryl-1-methyl)-piperazine), has been synthetized by condensation of veronal with formaldehyde and piperazine following a Mannich procedure. The new binuclear complex Cu2VEP(X)4·4H2O , X=ClO4- where VEP stands for N,N’-bis-(5,5’-diethyl-barbituryl-1-methyl)-piperazine, were obtained by metal - ligand direct synthesis. Tetrahedral geometry of the metal ion was preserved in solution as well in solid state. The binuclear complex contain VEP in a chair conformation. en_US
dc.language.iso en en_US
dc.publisher Timişoara: Editura Politehnica en_US
dc.relation.ispartofseries Seria chimie şi ingineria mediului, Tom 50(64), fasc. 1-2 (2005)
dc.subject Copper(II) complex en_US
dc.subject Mannich base ligand en_US
dc.subject Barbituric acid derivative en_US
dc.title Binuclear complexes containing barbituric derivatives as ligands-precursors for supramolecular structures. I. Synthesis and spectral properties of N,N’-bis-(5,5’-diethyl-barbituryl-1-methyl)-piperazine (VEP) and its copper(II) complex [articol] en_US
dc.type Article en_US


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